and tape.. The particles are allowed to move in a viscous solvent under the action of steric and magnetic interactions and of the orienting field. A percentage of the particles are grouped in clusters that behave as rigid bodies during the simulation. The results obtained suggest that the presence of the clusters leads to a disruption in the alignment of the free particles regardless of the cluster size. The synthesis of novel cyclic pyrrolidine imine sugars of L rhamnose stereochemistry was performed by a Staudinger aza Wittig reaction. The aza Wittig reaction of a known L rhamnose derived azido sugar gave a novel cyclic L rhamnopyrrolidine aldimine A novel synthesis of this azido sugar was also devised. Successful nucleophilic additions to the cyclic L rhamnopyrrolidine aldimine were performed with a range of Grignard reagents giving novel protected aza sugars in good yields and with excellent diastereoselectivities. The influence of temperature
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